Chemical equilibrium
A reversible reaction reaches equilibrium when forward and reverse rates become equal, so concentrations stop changing while both reactions continue — and a disturbance shifts the balance in the direction that partly offsets it.
Practise this conceptMany reactions do not run to completion. Products re-form reactants, and as product builds up that reverse reaction speeds up while the forward one slows. Eventually the two rates match and the composition stops changing. That is equilibrium — and the word "dynamic" attached to it is doing real work: nothing has stopped. Molecules are still reacting in both directions, at identical rates, which is why the concentrations hold steady.
Steady does not mean equal. The equilibrium constant K fixes the ratio of products to reactants, and that ratio can be enormous or tiny. A reaction with K = 10⁶ sits almost entirely on the product side at equilibrium; one with K = 10⁻⁶ has barely proceeded. Equal concentrations of reactants and products is one possible equilibrium among many, not the definition of one.
Disturb a system at equilibrium and it shifts to partly offset the change — Le Chatelier's principle. Add reactant and it consumes some; remove product and it makes more; raise the pressure on a gas mixture and it shifts towards whichever side has fewer molecules. This is what makes industrial synthesis controllable: the Haber process runs at high pressure precisely because ammonia occupies fewer molecules than the nitrogen and hydrogen it comes from. A catalyst does none of this. It lowers the activation barrier for both directions by the same amount, so equilibrium arrives faster but lands in exactly the same place.
Key ideas
Requires: Stoichiometry
Unlocks: Adsorption isotherms, Colloidal systems and electrokinetic phenomena, Phase equilibria and the Clausius-Clapeyron equation, Raoult's law and colligative properties, Reaction kinetics
Common misconceptions
- At equilibrium the reaction has stopped.
- At equilibrium the concentrations of reactants and products are equal.
- A catalyst shifts the position of equilibrium towards the products.
Resources
Part of these UT courses
This concept is mapped as covering part of the following course(s) in the University of Tartu curriculum.
- Physical chemistry, part 1LOKT.02.037
- Physical chemistry practical ILOKT.02.041
- Environmental chemistry ILOKT.04.004
- Analytical chemistry practical ILOKT.06.012
- Foundations of chemistryLOKT.07.010
- Laboratory practical (chemistry)LTKT.01.002
- Physical chemistry practical I (6 ECTS)LTKT.02.002
- Core course in analytical chemistryLTKT.06.019